Blair and Chuck would have great potential if they weren't so self-centered and stubborn to talk to each other. They're my face so far.
Blair and Nate was a hot looking couple, but they were on the rocks since the show started so you can't really say.
Serena and Dan, I liked them but now I'm just sick of them
Serena and Aaron Rose - blech, he's greasy looking. And Rachel Carr was just wrong wrong wrong.
I thought Nate and Jenny was a really cute couple, I'd like to see them again now that Jenny's past her teen rebel stage. But I don't think it'll ever come up again because viewers had problems with their real life age difference.
I don't know if Jenny and Nate are a couple in real life, for a while it looked a lot like it, but I don't think so. Serena and Dan and Chuck and Vanessa are though